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Test 1 |
Alcohol Reactions |
Pre-Printable Lecture NotesUsed in These Alcohol Lectures |
1 |
Tues Jun 11 |
Intro and Alcohols Lecture 1 |
Class Intro; Alc. Classification, Nomenclature |
2 |
Wed Jun 12 |
Alcohols Lecture 2 |
Physical Properties, Organometallics, Grignard Reactions,and Synthetic Analysis |
3 |
Thurs Jun 13 |
Alcohols Lecture 3 |
p10-14 RMgBr Mechanisms, Products, and Synthetic Analysis |
4 |
Friday Jun 14 |
Alcohols Lecture 4
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p14-18 Synthetic Analysis, Synthesis Design, NaBH4/LiAlH4 Reduction |
5 |
Mon Jun 17 |
Alcohols Lecture 5 |
NaBH4, LiAlH4 Reduction Reactions. |
6 |
Tues Jun 18 |
Alcohols Lecture 6 |
p18, p1-5 NaBH4, LiAlH4 Reduction Reaction Mechanisms. Alcohol Acid-Base, Alkoxides. |
7 |
Wed Jun 19 |
Alcohols Lecture 7 |
ROH to RONa to ROR, ROH Oxidation, Oxidation-Grignard Combinations. |
8 |
Thurs Jun 20 |
Alcohols Lecture 8 |
ROH to R-Halide to RMgBr, Retrosynthesis. Retrosynthesis. |
9 |
Friday Jun 21 |
Alcohols Lecture 9 |
Chemical Tests, Tosylates, Miscellany, Retrosynthesis |
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Test 1 Preview |
4 minute |
10 |
Mon Jun 24 |
Alcohols Lect 10 |
Retrosynthesis Practice, Mechanisms. 10 minutes of NMR at end. |
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Practice Test 1-Version 1 |
Movie of Jasperse Going Through it (Panopto, similar to Tegrity) |
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Practice Test 1-Version 2 |
Movie of Jasperse Going Through it (Panopto, similar to Tegrity) |
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Practice Test 1-Version 3 |
Movie of Jasperse Going Through it (Panopto, similar to Tegrity) |
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Practice Test 1-Version 4 |
Movie of Jasperse Going Through it (Panopto, similar to Tegrity) |
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Test 2 |
Test 2 Spectroscopy- NMR |
Test 2 Spectroscopy and NMR Preprintable Notes Used in These Lectures
NMR Problems Used in These Lectures |
11 |
Tues Jun 25 |
NMR Lecture 1 |
Intro to NMR, H-NMR Interpretation |
12 |
Thurs Jun 27 |
NMR Lecture 2 |
H-NMR Practice, Symmetry, Overlap, Integration, Splitting |
13 |
Fri Jun 28 |
NMR Lecture 3 |
Chemical Shifts, Integration, Splitting |
14 |
Mon July 1 |
NMR Lecture 4 |
H-NMR Predictions and C-13 NMR |
15 |
Tues July 2 |
NMR Lecture 5 |
C-NMR Problems. |
16 |
Wed July 3 |
NMR Lecture 6 |
IR, C13, 2D, Practice, NMR Splitting |
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NMR Problems 1-26 |
Jasperse practice problems 1-26. Practice problems in the notes that did not get covered in class for reasons of time, as welll as those that were already covered in class. In order. |
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NMR Problems 27-42 |
Jasperse practice problems 27-42. |
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"Quicktime" Practice Test Movies |
How to Load and Watch the Quicktime NMR Practice Test Movies: Instructions |
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Practice Test 2-Version 1 and Podcast |
Movie of Jasperse Going Through it (Panopto, similar to Tegrity) |
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Practice Test 2-Version 2 and Podcast |
Movie of Jasperse Going Through it (Panopto, similar to Tegrity) |
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Practice Test 2-Version 3 and Podcast |
Movie of Jasperse Going Through it (Panopto, similar to Tegrity) |
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Practice Test 2-Version 4 and Podcast |
Movie of Jasperse Going Through it (Panopto, similar to Tegrity) |
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Test 3 |
Test 3 Carbonyls |
Test 3 Aldehydes, Ketones, and EnolatesPreprintable Notes |
17 |
Friday July 5 |
Carbonyl Lecture 1 |
Carbonyl Nomenclature, Properties, Synthesis. |
18 |
Mon July 8 |
Carbonyl Lecture 2 |
Carbonyl Synthesis; Addition Reactions to Carbonyls |
19 |
Wed July 10 |
Carbonyl Lecture 3 |
Addition Reactions to Carbonyls. Anionic, RMgBr, Hydride, HCN, H2O; Acid catalyzed, reversible formation of hydrates under acid or base conditions. |
20 |
Thurs July 11 |
Carbonyl Lecture 4 |
Reversible Formation of Acetals, Hemiacetals; Protection Chemistry; Mechanisms |
21 |
Fri July 12 |
Carbonyl Lecture 5 |
Imines, Aminols, Imines + Mechs; Aldehyde Oxidation; Chemical Tests |
22 |
Mon July 15 |
Enolates Lecture 1 |
Enolates Reaction Mechanisms. Proton, Halogen, Alkyl Halides as Electrophiles |
23 |
Tues July 16 |
Enolates Lecture 2 |
Alkyl Halide Electrophiles. LDA, Ox Bases; Mono-carbonyls vs Dicarbonyls; Decarbox |
24 |
Wed July 17 |
Enolates Lecture 3 |
Aldol Reaction/Condensation: Aldehydes/Ketones as Electrophiles |
25 |
Thurs July 18 |
Enolates Lecture 4 |
Ester Electrophiles |
26 |
Fri July 19 |
Enolates Lecture 5 |
Wittig Reaction, Chemical Tests, Practice Problems |
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Extra Mechanism Practice |
Extra Mechanism Practice Problems Discussed |
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Retrosynthesis and Design |
Extra Retrosynthesis and Synthetic Design Problems Discussed |
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Test 3 Preview |
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Practice Test 3-Version 1 |
Movie of Jasperse Going Through it (Panopto, similar to Tegrity) |
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Practice Test 3-Version 2 |
Movie of Jasperse Going Through it (Panopto, similar to Tegrity) |
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Practice Test 3-Version 3 |
Movie of Jasperse Going Through it (Panopto, similar to Tegrity) |
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Test 4 |
Test 4 Amines + Acids |
Test 4 Amines, Acids, Esters Preprintable Notes Used in These Lectures |
27 |
Mon July 22 |
Amines Lecture 1 |
Enolates Retrosynthesis. Amines 1. Nomenclature, Hybridization, Properties, Basicity |
28 |
Tues July 23 |
Amines Lecture 2 |
Amines 2. Acid-Base Chemistry |
29 |
Thurs July 25 |
Amines Lecture 3 |
Amines 3. Amine/Ammonium, Reactions of Amines |
30 |
Fri July 26 |
Amines Lecture 4 |
Amines 4. Reactions and Synthesis of Amines |
31 |
Mon July 29 |
Acids Lecture 1 |
Acids 1. Nomenclature and Synthesis |
32 |
Tues July 30 |
Acids Lecture 2 |
Acids 2. Hydrolysis of Acid chlorides, anhydrides, esters, and amides. |
33 |
Wed July 31 |
Acids Lecture 3 |
Acid Chlorides, Anhydrides, Esters, and Amides. Synthetic interconversion. |
34 |
Thurs Aug 1 |
Acids Lecture 4 |
68 minutes. This covers all of the notes problems on pages 30-36 and on page 17. It may repeat some problems that were covered in lecture 33. |
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Test 4 Preview |
5-min Preview of what Test 4 will look like |
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Acid-Base Practice (Easy) + Pod |
Acid-Base Practice (Easy) and Answers |
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Acid-Base Practice (Harder) + Pod |
Acid-Base Practice (Less Easy) and Answers |
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Practice Test 4-Version 1 |
Movie of Jasperse Going Through it (Panopto, similar to Tegrity) |
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Practice Test 4-Version 2 |
Movie of Jasperse Going Through it (Panopto, similar to Tegrity) |
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Practice Test 4-Version 3 |
Movie of Jasperse Going Through it (Panopto, similar to Tegrity) |