Minnesota State University Moorhead
Dr. Craig P. Jasperse, Chemistry
email: jasperse@mnstate.edu   Phone: (218) 477-2230   Office: Hagen 407J                             

Online Organic
AboutFall/Spring
Apply+Register
AboutSummerOn

Summer:
O1-online (
classic)
O2-online
(
classic)

Spring:
O1-online
O2-online
O2-in-person
Chem 365-Lab

Fall:
O1-online
O2-online
O1-in-person
Chem 355-Lab

email link to:
jasperse@mnstate.edu


From Past:
Chem210-Gen2

Jasperse Home

Research

 

 

 

 

 

 

 

Organic Chemistry I Chem 350online Lectures
Test 1 Lectures /// Test 2 Lectures /// Test 3 Lectures /// Test 4 Lectures

1. These lectures are typically 50 minutes in length.
2. For alternate videos, (if one is bad or something) see either: Chem350 Lectures Earlier Year or NDSU Organic I Tegrity Lectures
3. Print the pre-printable lecture notes prior to viewing the lectures for most effective usage.
The preprintable practice tests are available from the Chem350 Practice Tests Link.
4. The mp4 files aren't big and can be downloaded so that they can be viewed without an internet connection.
5. Video links to days future are videos from last year. I will replace them one by one as I give the new lectures.
6. If you have trouble, contact Dr. Jasperse for help.
Chem 350 Lectures 2015

      Movies mp4 Files Sapling Topic
      Test 1 Intro and Alkanes.     Test 1 Intro and Alkanes
    Date Relevant Test 1notes     Pre-Printable Lecture Notes that Were Used in These Test 1 Lecture Movies
1 M 8/24 Intro + Syllabus IntroPod   Class Introduction, Syllabus, Etc.
1 M 8/24 OChem -Intro Lecture 1 Pod-1 training
sessions
(Real Notes.) Why Carbon is Special, Normal bonding, Lewis Structures in Organic
2 W

8/26

OChem-Intro Lecture 2 Pod-2

1:1-10

1. Normal Bonding.  2.  Formal Charge and Abnormal Bonding. 3. Electronegativity

3 F 8/28 OChem -Intro Lecture 3 Pod-3 1:11-21 1.  Structural formulas: Full, Condensed, and Skeletal   2.  Resonance Structures 3. Arrow Pushing
      Extra Resonance Video     Extra Resonance Video (ChemSurvival, 6 min)
      Arrow-pushing and Podcast     Mechanistic Arrow-Pushing Problems and Answers, 29-min Movie Linked to the Left
4 M 8/31 OChem -Intro Lecture 4 Pod-4 1:22-27 1.  Mechanism/Arrow-pushing.  2. Resonance 3.  Acid-Base Chemistry. 4.  Anion Stability Patterns.  
      Extra Acid-Base Video and Pod     Extra Acid Base Problems and Answers, 36-min Movie Linked to the Left
5 W 9/2 OChem -Intro Lecture 5 Pod-5   Acid-Base Chemistry.  Anion Stability Patterns. VSEPR 3D Shape.  Drawing 3D.
      3-D Structure Drawing and Podcast     Extra 3-D Structure-Drawing Problems and Answers, 45-min Movie Linked to the Left
    top

Extra VSEPR Video 1
Extra VSEPR Video 2

    Extra VSEPR Video 1. (4 min)
Extra VSEPR Video 2 (Jasperse, 6 min)
6 F 9/4 OChem -Intro Lecture 6 Pod-6 2:1-14 Drawing 3D; Hybridization; Pi bonds; Isomers; Polarity IMF, Boiling Points
7 W 9/9 OChem -Intro Lecture 7 Pod-7 2:15-18

Solubility. Functional Groups.

8 F 9/11 OChem -Alkanes Lect 8 Pod-8 3:1-10 Alkane Nomenclature.  Newman Projections; Torsional and Steric Strain; Cycloalkanes
      Newman Practice Movie and Pod     Extra Newman Practice Problems and Answers
      Extra Newman Video 1 (ethane)
Extra Newman Video 2 (ethane)
Extra Newman Video 3 (butane)
    Extra Newman Video 1 (ChemSurvival, ethane, 3 min)
Extra Newman Video 2 (ChemSurvival, ethane, 5 min)
Extra Newman Video 3 (ChemSurvival, butane, 6 min)
9 M 9/14 OChem -Alkanes Lect 9 Pod-9 3:11-22 Cyclohexane Chairs, Cis-and-Trans, Structural Isomers
      Cyclohexane Movie and Pod     Extra Cycloehxane Chair Practice Problems and Answers
Cyclohexane and Newman Projections Summary
      Cyclohexane chairs and chair flips
Substituted Cyclohexanes
    Extra Chair Video 1: Cyclohexane (ChemSurvival, 3 min)
Extra Chair Video 2: Substituted Cyclohexane (ChemSurvival, 4 min)
10 W 9/16 OChem -Alkanes Lect 10 Pod-10 4:1-5 Catchup/Practice, first 38 minutes; Test 2 material starts at 38 minutes.
      Test 1 Preview and Practice Tests      
      Test1Preview      
      Practice Test 1-Version 1     Tegrity Movie of Jasperse Going Through it
      Practice Test 1-Version 2 Pod1v2   Regular Panopto Movie of Jasperse Going Through it. 49 min
      Practice Test 1-Version 3     Tegrity Movie of Jasperse Going Through it
      Practice Test 1-Version 4 Pod1v4   Regular Panopto Movie of Jasperse Going Through it. 33 min
    top        
      Test 2 Radical Halogenation,
Basic Principles of Reactivity,
Stereochemistry
, SN2/SN1/E2/E1
    Test 2 Radical Halogenation, Basic Principles of Reactivity,
Stereochemistry, and SN2/SN1/E2/E1 reactions of Alkyl Halides
      Relevant Test 2notes     Pre-Printable Lecture Notes that Were Used in These Test 2 Lecture Movies
10 W 9/16 OChem -Alkanes Lect 10 Pod-10 4:1-5 Test 2 material starts at 37:45 minutes. p1-2
11 M 9/21 OChem-Reactions Lecture 2 Pod-11 4:6-8 p2-7 Radical Halogenation Mech; Bond Strengths; Radical Stabilities;
12 W 9/23 OChem -Reactions Lecture 3 Pod-12 4:9-14

Rate Laws, Transition States, Stability-Reactivity Principles. Radical Brominations. Major product, mechanism, structural isomers.

      Radical Practice Video Pod   Br2/hv Products/Mechanisms Practice and Answers
13 F 9/25 OChem -Reactions Lecture 3/Stereo 1
Stereo starts at 40.1 min
Pod-13 4:9-14

p13-18 Radical Brominations. Product, mechanism. Stability patterns for radicals/cations/anions. Stability-reactivity principles.
Ch 5, p1. Chiral vs achiral, Enantiomers

      Radical Practice Video Pod   Br2/hv Products/Mechanisms Practice and Answers
14
M 9/28 Stereo Lecture 2

Pod-14

5:1-5 p1-3 , Chiral Carbons; Chiral vs achiral; Same vs Enantiomers; Attachment Priorities; R/S Designation
      Stereochem Practice Video Pod   Stereochem Practice and Answers (video is a little slow to load, be patient at start)
15 W 9/30 OChem - Stereo Lecture 3 Pod-15 6-16

p3-5 Chiral Carbons; Attachment Priorities; R/S Designation; Drawing Chiral Molecules. Racemic mixtures and Optical Activity.

16 F 10/2 OChem - Stereo Lecture 4 Pod-16 17-28 p6-11 Conformations + Chirality; Planes of Symmetry; Meso; Cis/Trans Diastereomers vs Enantiomers; Recognizing Chiral vs Meso
17 M 10/5 OChem - RX-Sn-E Lecture 1 Pod-17 6:1-5 p1-6,10 Alkyl Halides. Reaction preview; Alkyl/Vinyl/Aryl/Allyl Classification; 1º/2º/3º Classification; overview of SN2/SN1/E2/E1 reactions; SN2 reactions and mechanism and product prediction in detail
18 W 10/7 OChem -Sn-E Lecture 2 Pod-18 6:6-17 p6-12 SN2 Reaction. Product Prediction, Structural Factors. Ranking. Inversion. Mechanisms.
19 F 10/9 OChem -Sn-E Lecture 3 Pod-19 6:18-26 p12-16 SN1 Reactions. E1 Reactions Started.
20 M 10/12 OChem -Sn-E Lecture 4 Pod-20 6:27-31 p16-23. E1, E2 Reactions. Zaytsev's Rule. Using Anion/Neutral and 1º, 2º, 3º to diagnose among SN2/E2/SN1/E1
21 W 10/14 OChem -Sn-E Lecture 5 Pod-21 6:32-41 p20-26 E2 Stereochemistry; Diagnosing Reaction Types; Two-Step Synthesis Design; E1 + E2 Mechanisms; Ranking Problems
22 M 10/19 OChem Alkenes Lecture 1
First 9 minutes Relavent to Test 2
Pod-22 7:1-11

First 9 minutes relavent to Test 2. Rest is Test 3 content.
1) Anions that don't trigger SN2/E2 (strong base anions). 2) Carbocation Rearrangements

    top Practice Problems Undone in Class
p27-28 time 33:00-54:00
Pod-21-B   p27-28 Practice Problems in Notes that went Uncovered in Class. Time 33:00-54:00
      Extra Mechanism Practice Problems Pod-21-C   Extra Mechanism and Product Prediction Problems
      Extra Stereochem Practice Problems Pod   Extra R/S, Chiral vs Achiral, and Same/Enantiomer/Diastereomer Practice Problems
      Extra Radical Bromination Practice Pod   Extra Br2/hv Product Prediction and Mechanism Practice Problems
      Test 2 Preview     Test 2 Preview - 6 minutes
      Practice Test 2-Version 1     Practice Test 2-Version 1-Movie of Jasperse Going Through it
      Practice Test 2-Version 2     Practice Test 2-Version 2-Movie of Jasperse Going Through it
      Practice Test 2-Version 3 Pod2v3   Regular Panopto Movie of Jasperse Going Through it. 34 min
      Practice Test 2-Version 4 Pod2v4   Regular Panopto Movie of Jasperse Going Through it. 28 min
    top        
      Test 3: ALKENES     Test 3: Alkenes. Properties, Synthesis, Reactions
      Relevant Test 3 notes     Pre-Printable Lecture Notes that Were Used in These Test 3 Lecture Movies
22 M 10/19 OChem Alkenes Lecture 1
(56 minutes long)
Pod-22 7:1-11 Test 2 (first 9 minutes): Nonreactive "Strong acid" anions. Carbocation Rearrangements. (Ch 6 p29)
Test 3 content starts at 9 minutes in. p1-5. Intro to alkenes, (EU), Hydrogenation; Alkene Nomenclature; E/Z stereochem
23 W 10/21 OChem Alkenes Lecture 2
(45 minutes long)
Pod-23 7:12-23 p6-11 Alkene Stabilities; Heats of Hydrogenation/Combustion; Bulky Bases/Normal Bases for Hofmann/Zaytsev Elimination
24 F 10/23 OChem Alkenes Lecture 3 Pod-24 7:18-25 p11-16 Alkene Formation. From Alcohols via Acid-Catalyzed E1. Mechanism Recognition.
25 M 10/26 OChem Alkenes Lecture 4
Pod-25 8:1-9 p16; p1-13 (not 11); Overview, Intro, Addition reactions to Alkenes. Addition of HBr; Acid-Catalyzed HOH Addn;
26 W 10/28 OChem Alkenes Lecture 5 Pod-26 8:10-18 p13-18,11 Acid-Catalyzed HOH Addn; Oxymercuration/Demercuration; Anti-Markovnikov Hydroboration-Oxidation; Synthesis Design
27 F 10/30 OChem Alkenes Lecture 6 Pod-27 8:19-29 11, 20-23 Synthesis Design, H2 addn; Br2 addn
28 M 11/2 OChem Alkenes Lecture 7
(56 minutes long)
Pod-28 8:22-36 23-28 Br2 and BrOH additions and mechanisms; epoxidation; Dihydroxylation; Stereospecific Rxns
29 W 11/4 OChem Alkenes Lecture 8
(56 minutes long)
Pod-29
8:35-41 p28-33. Dihydroxylation, Ozonolysis.
Stereospecific Alkene Reactions. Synthetic Design.
      Test 3 Extra Synthesis Design Practice Pod   Discussion of Extra Synthesis Design Practice Problems
      Test 3 Preview Pod   Test preview
      Practice Test 3 V1 Pod3v1   Practice Test 3-Version 1-Movie of Jasperse Going Through it (Tegrity movie)
      Practice Test 3 V2 Pod3v2   Practice Test 3-Version 2-Movie of Jasperse Going Through it (Tegrity movie)
      Practice Test 3 V3 Pod3v3   Practice Test 3-Version 3-Movie of Jasperse Going Through it. 36 min
      Practice Test 3 V4 Pod3v4   Practice Test 3-Version 4-Movie of Jasperse Going Through it. 33 min
    top        
      Test 4: Conjugation and Aromatics     Conjugation, Aromatics, and Reactions of Aromatics
      Relevant Test 4 Notes     Pre-Printable Lecture Notes that Were Used in These Test 4 Lecture Movies
30 F 11/6 OChem Conjugation Lecture 1
37 min
Pod-30   p1-6 Conjugation: Introduction, impact on stability, reactivity, hybridization, lone-pairs.
Conjugated Dienes, allylic cations. 37 min.
31 F 11/13 OChem Conjugation Lecture 2 Pod-31 15:1-9

p6-10 Asymmetric allylic cations can give Two Products. 1,2/1,4-Addn to Dienes.

32 M 11/16 OChem Conjugation Lecture 3 Pod-32 15:10-13 p10-17. Allylic Cations. Allylic Radicals (NBS bromination). Allylic anions. Allylic SN2. Diels-Alder Intro. (p15,16 skip)
      HBr to Dienes, Allylic Bromination Pod   HBr Addition to Dienes and NBS Allylic Bromination Practice Answers Movie
33 W 11/18 Diels Alder Lecture Pod-33 15:14-20 p17-21. Diels-Alder Reactions of Conjugated Dienes. (p22-25 skip)
34 F 11/20 OChem Aromatics Lecture 1
Pod-34 16:1-12 p1-6 Aromaticity,Frost Diagrams,Huckel's Rule,Ions,Heterocycles,N lone-pair hybridization and basicity
35 M 11/23

OChem Aromatics Lecture 2 and intro to Aromatic Reactions

Pod-35

16:13-19

p6-8 Nitrogen lone-pair hybridization and basicity; Aromatic Nomenclature.
p1-7 Intro to Electrophilic Aromatic Substitution Reactions. Mechanism;

36 M 11/30 OChem Aromatics Substitution 2 Pod-36 17:1-21 p6-11 Aromatic Substitution Reactions. Mechanisms and Electronics. Halogenation.
37 W 12/2 OChem Aromatics Substitution 3 Pod-37   p12-17 Aromatic SubstitutinSubstituent Directing StrengthAromatic Nitration, Alkylation, Acylation, Addition to Disubbed Benzenes
38 F 12/4 OChem Aromatics Substitition 4 Pod-38   p17-21 Aromatic Substitution. Synthesis Design. Protection-Deprotection. Side chain oxidation/bromination. Synthesis Design.
      Test4Preview Pod    
     

Aromatic Substitution Mechanisms

Pod   Aromatic Substitution Mechanisms (Products Provided) and Answers
      Aromatic Product Prediction/ Mechanisms/Synthesis Design Pod   Aromatic Substitution Product Prediction/Mechanisms/Synthesis Design Practice and Answers
      Practice Test 4-Version 1 Pod4v1   Regular Panopto Movie of Jasperse Going Through it. 50 min
      Practice Test 4-Version 2 Pod4v2   Regular Panopto Movie of Jasperse Going Through it. 42 min
      Practice Test 4-Version 3 Pod4v3   Regular Panopto Movie of Jasperse Going Through it. 50 min
    top        
      Final Exam Practice Tests      
      Final Exam Preview Pod   http://coursecast.mnstate.edu/Panopto/Pages/Viewer/Default.aspx?id=08bb7459-cd50-48c1-b676-ab0de2f20a5e
      Final Exam Practice Version 1     http://coursecast.mnstate.edu/Panopto/Pages/Viewer/Default.aspx?id=c29cb1a9-390b-4ccb-ba8e-b3a28c01cd8e
Note: this is a regular web link, not a Quicktime link. Double click on the view screen to get a full-screen look.
      Final Exam Practice Version 2     http://coursecast.mnstate.edu/Panopto/Pages/Viewer/Default.aspx?id=19ceaa38-d52b-42fc-be8c-b21eb910a6d6
Note: this is a regular web link, not a Quicktime link. Double click on the view screen to get a full-screen look.