Dr. Craig P. Jasperse, Chemistry
email: jasperse@mnstate.edu Phone: (218) 477-2230 Office: Hagen 407J
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Minnesota State University Moorhead
Dr. Craig P. Jasperse, Chemistry email: jasperse@mnstate.edu Phone: (218) 477-2230 Office: Hagen 407J |
Online Organic
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Organic Chemistry II Chem 360 Lectures
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| Date | Streaming Videos |
Topic | ||
| Test 1 | Test 1 | Alcohol Reactions | Alcohol Synthesis and Reactions. Including Grignard/Organometallic Chem and Redox. | |
| Semester-Long Notes | Complete Semester-Long Notes for Printing | |||
| Relevant Test 1 Notes | Pre-Printable Lecture Notes that Were Used in These Test 1 Lecture Movies | |||
| 1 | M | Jan 8 | 1a Syllabus/Intro: (16 minutes) p1-6. Alcohol Classification and Nomenclature. (34 min) |
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| 2 | W | Jan 10 | Alcohols Lecture 2 | p6-9, 15. Organometallics, Grignard Reactions; Drawing Products of Grignard Reactions, Retrosynthetic Analysis. |
| Practice Set 1 Video | General Mechanism Practice/Review and Answers and Video and Pod | |||
| 3 | F | Jan 12 | Alcohols Lecture 3 | p10-15. RMgBr Review. Ethylene Oxide (p10) RMgBr Mechanisms,including esters and epoxide (p11-13). Product prediction (p14) |
| Practice Set 2 Video | Mechanisms Problems (Test 1 Specific) and Answers | |||
| Quiz1 | Quiz1: Grignard Reactions. Doable now; due by Test 1 | |||
| 4 | W | Jan 17 | Alcohols Lecture 4 |
p14-20. More RMgBr Synthetic Analysis, Products (14), Selectivity (12,14), Retrosynthesis (15), Synthesis Design (16). |
| Quiz1 | Quiz1: Grignard Reactions. Doable now; due by Test 1 | |||
| 5 | F | Jan 19 | Alcohols Lecture 5 | p17-20, p4-5 OH C=O incompatible (17). NaBH4 +LiAlH4 Reductions. (p18-20) Alcohol reactions. OH Acid-Base(p4-5) |
| Practice Set 3 Video | Acid-Base Practice/Review -- Answers -- Movie | |||
| 6 | M | Jan 22 | Alcohols Lecture 6 | p6-10. ROH to RONa to ROR; ROH Oxidation; Oxidation-Grignard Combinations |
| 7 | W | Jan 24 | Alcohols Lecture 7 |
p9-16 Overview of Oxidation-Reduction chemistry; ROH -> RBr Products + Mech. to RMgBr; Retrosynthesis. |
| Practice Set 4 Video | Retrosynthesis Problems and Answers and Video and Pod | |||
| 8 | F | Jan 26 | Alcohols Lecture 8 | p16-19 Retrosynthesis, Synthesis Design |
| 9 | M | Jan 29 | Alcohols Lecture 9 | p19,20 Chemical Tests, Tosylates |
| EU-Intro-Video (25min) | Elements of Unsaturation Notes-- Answers -- Movie (25min) | |||
| 10 | W | Jan 31 | Alcohols Lect 10 |
p18, 21-25 SOCl2, Mechanisms Practice, Miscellaneous Practice, Concept Maps |
1. General Mechanism Practice/Review and Answers and Video and Pod |
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| Test 1 Preview | ||||
| Practice Test 1-Version 1 | Test1v1 and answers, and Movie of Jasperse Going Through it. 49 min | |||
| Practice Test 1-Version 2 | Test1v2 with answers, and Movie of Jasperse Going Through it. 49 min | |||
| Practice Test 1-Version 3 | Test1v3 and answers, and Movie of Jasperse Going Through it. 49 min | |||
| Practice Test 1-Version 4 | Test1v4 and answers, and Movie of Jasperse Going Through it. 49 min | |||
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| Test 2 | Test 2 | Test 2 Spectroscopy |
Test 2 Spectroscopy: H-NMR, C-NMR, and IR | |
| Relevant NMR notes | Pre-Printable Lecture Notes that Were Used in These NMR Lecture Movies | |||
| Relevant NMR Problems |
Pre-Printable NMR Spectra that Were Used in These NMR Lecture Movies | |||
| Relevant NMR Answers | Answers to the NMR Spectra that were used in These NMR Lecture Movies | |||
| 11 | F | Feb 2 | NMR 1 |
Intro to NMR; H-NMR Interpretation |
| EU-Intro-Video (25min) | Elements of Unsaturation Notes-- Answers -- Movie (25min) | |||
| 12 | M | Feb 5 | NMR 2 | H-NMR Interpretation |
| 13 | F | Feb 9 | NMR 3 | p6-9, 14 NMR3 Overlap, Symmetry, Integration, Splitting, Spectrum Prediction |
| Familiar H-NMR Groups | Familiar H-NMR Groups, Easy to Recognize and Video and Pod | |||
| 14 | M | Feb 12 | NMR 4 | p10-14 H-NMRSpectrum Prediction; Chemical Shifts; Practice |
| 15 | W | Feb 14 | NMR 5 | p12- Carbon NMR. |
| 16 | F | Feb 16 | NMR 6 | IR, C-NMR Problems, Splitting, Problems |
| 17 | M | Feb 19 | NMR 7 | NMR practice problems. (First 20 minutes) p1-p13. Aldehyde and Ketone Nomenclature. 20 min on) |
| NMR Problems 1-26 | Jasperse practice problems 1-26. Practice problems in the notes that did not get covered in class for reasons of time. |
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| NMR Problems 27-42 | Jasperse practice problems 27-42. | |||
| Test 2 Preview | ||||
| Practice Test 2-Version 1 | Test2v1 and answers, and Movie of Jasperse Going Through it. 49 min | |||
| Practice Test 2-Version 2 | Test2v2 with answers, and Movie of Jasperse Going Through it. 49 min | |||
| Practice Test 2-Version 3 | Test2v3 and answers, and Movie of Jasperse Going Through it. 49 min | |||
| Practice Test 2-Version 4 | Test2v4 and answers, and Movie of Jasperse Going Through it. 49 min | |||
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| Test 3 | Test 3 | Test 3: Carbonyl Chem | Test 3: Carbonyls: Addition Reactions and Enolate Reactions | |
| Relevant Carbonyls notes | Pre-Printable Lecture Notes that Were Used in These Carbonly and Enolate Lecture Movies | |||
| 17 | M | Feb 19 | Carbonyls Lect 1 | NMR practice problems. (First 20 minutes) p1-p13. Aldehyde and Ketone Nomenclature. 20 min on) |
| 18 | F | Feb 23 | Carbonyls Lect 2 | Carbonyls Synthesis and Mechanisms for Hydrolysis of Enols, Hydrates |
| 19 | M | Feb 26 | Carbonyls Lect 3 | Carbonyl Synthesis; Addition Reactions to Carbonyls |
| 20 | W | Feb 28 | Carbonyls Lect 4 | Reversible Formation of Hydrates and Acetals. Addn/Elim/Substitution Reactions. Protection. |
| Mech.Practice Practice Set 1- Movie |
Mechanism Practice (Many) Test 3- - - Answers- - -Movie - - - Pod | |||
| Quiz2 | Quiz2: Carbonyl Mechanisms, Long. | |||
| 21 | F | Mar 1 | Carbonyls Lect 5 | Acetals/Hemiacetals; Carboyhydrates; Protecting Groups; Imines. Aldehyde Oxidation; Chemical Tests; |
| 22 | M | Mar 4 | Carbonyls-6-Enolates-1 |
p34-36 Carbohydrates + Polymers, DNA/RNA p12-15 Enolates Introduction, Mechanisms, Acid-Base Considerations |
| 23 | W | Mar 6 | Enolates 2 | p15-19 Enolates Reaction Mechanisms. Enolates, Enolate Reactions, Acid-Base, Enols, Proton Electrophiles. |
| 24 | F | Mar 8 | Enolates 3 | p20-24 Halogen Electrophiles; Polysubstitution; Iodoform; LDA vs Ox Bases; Alkyl Halide Electrophiles. LDA, Ox Bases; Mono-carbonyls vs Dicarbonyls; DecarboxEnolate Review, |
| Practice Set 1- Movie | Mechanism Practice (Many) Test 3- - - Answers- - -Movie - - - Pod | |||
| 25 | M | Mar 18 | Enolates 4 |
p-22-26 Aldol Reaction/Condensation: Aldehydes/Ketones as Electrophiles |
| 26 | W | Mar 20 | Enolates 5 |
p28-31 More Aldol Reaction; Intro to Claisen reaction (ester electrophile) |
| Practice Set 1- Movie | Mechanism Practice (Many) Test 3- - - Answers- - -Movie - - - Pod | |||
| 27 | F | Mar 22 | Enolates 6 | p30-35 More Claisen reaction (ester electrophile); Intro to Wittig Reaction |
| 28 | M | Mar 25 | Enolates 7 | p31-36. Wittig Reaction and Retrosynthesis/Design |
| Practice Set 2 - Movie | Retrosynthesis Practice Test 3- - - Answers- - -Movie- - -Pod | |||
| 1. Mechanism Practice (Many) Test 3- - - Answers- - -Movie - - - Pod 2. Retrosynthesis Practice Test 3- - - Answers- - -Movie- - -Pod Quiz2: Carbonyl Mechanisms, Long. Due by Test 2 |
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| Test 3 Preview | Test Preview | |||
| Practice Test 3-Version 1 | Test3v1 and answers, and Movie of Jasperse Going Through it. 49 min | |||
| Practice Test 3-Version 2 | Test3v2 with answers, and Movie of Jasperse Going Through it. 49 min | |||
| Test3v3 and answers, and Movie of Jasperse Going Through it. 49 min | ||||
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| Test 4 | Test 4 | Test 4: Amines + Acids | Test 4: Amines, Carboxylic Acids, Esters, and Amides | |
| Relevant Notes | Pre-Printable Lecture Notes that Were Used in These Amines and Acids Lecture Movies | |||
| 29 | W | Mar 27 | Amines Lect 1 | Amines 1. Nomenclature, Hybridization, Physical Properties |
| Practice Set 1- Movie | Acid-Base Practice/Review/Basics (Easy) -- Answers -- Movie -- Pod | |||
| 30 | F | Apr 5 |
Amines Lect 2 | Amines 2. Properties, Basicity. Hybridization of N-lone pairs; Reactivity of Amines; Acid-Base Chemistry |
| 31 | M | Apr 8 | Amines Lect 3 | Amines 3. Amine/Ammonium acid/base chemistry. |
| Practice Set 2- Movie | Acid-Base Practice (Harder, Test Oriented) -- Answers -- Movie -- Pod | |||
| 32 | W | Apr 10 | Amines Lect 4 | Amines 4. Acid-Base. Alkylation/Polyalkylation of Amines. |
| 33 | F | Apr 12 | Amines Lect 5 | Amines 5. p27-35 Amidation of Amines. Synthesis of Amines. Reductive amination, Reduction of Amides, etc. |
| 34 | M | Apr 15 | Amines6-Acids 1 |
Amines 6: |
| 35 | W | Apr 17 | Acids Lecture 2 |
Acids 1: p1-12, 25-50 min: Acid Introduction, Nomenclature, Acidity-Basicitiy.Acids 2. p12-20. Acid Synthesis.Hydrolysis of Acid chlorides, anhydrides, esters, and amides |
| 36 | F | Apr 19 | Acids Lecture 3 |
Acids 3. p20-25 Rxn Mechanisms. Reactions of Acids. SOCl2, conversions within ClAvEN-O. |
| Practice Set 3- Movie | Mechanisms, Retrosynthesis + Synthesis Design --- Answers --- Movie -- Pod | |||
| 37 | M | Apr 22 | Acids Lecture 4 |
Uphill conversion. Acids 4. p23-29 |
| 38 | W | Apr 24 | Acid Lecture 5 | Acids 5. p29-33 Practice Problems |
| 39 | F | Apr 26 | Acid Lecture 6 (41min) |
Catchup. Practice. p33-36 Polymers Chemistry. |
| Practice Set 3- Movie | Mechanisms, Retrosynthesis + Synthesis Design --- Answers --- Movie -- Pod | |||
| 1. Acid-Base Practice (Easy) -- Answers -- Movie -- Pod 2. Acid-Base Practice (Less Easy) -- Answers -- Movie -- Pod 3. Mechanisms, Retrosynthesis + Synthesis Design --- Answers --- Movie -- Pod |
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| Test 4 Preview | 2-minute overview of what Test 4 will look like. | |||
| Practice Test 4-Version 1 | Test4v1 and answers, and Movie of Jasperse Going Through it. 49 min | |||
| Practice Test 4-Version 2 | Test4v2 with answers, and Movie of Jasperse Going Through it. 49 min | |||
| Practice Test 4-Version 3 | Test4v3 and answers, and Movie of Jasperse Going Through it. 49 min | |||
| FINAL | Final Exam Preview |
Final Exam Preview: Note: Final used fall and spring, but NOT SUMMER | ||
| Final Exam-Version 1 |
Final-Exam-v1 and answers, and Movie of Jasperse Going Through it. -Note: on certain pages, especially page 6, the actual final won't have as many problems |
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| Sapling Movie |