Dr. Craig P. Jasperse, Chemistry
email: jasperse@mnstate.edu Phone: (218) 477-2230 Office: Hagen 407J
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Minnesota State University Moorhead
Dr. Craig P. Jasperse, Chemistry email: jasperse@mnstate.edu Phone: (218) 477-2230 Office: Hagen 407J |
Online Organic
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Organic Chemistry II Chem 360online Lectures
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| Streaming Videos |
Topic | |
| Test 1 | Alcohol Reactions | Alcohol Synthesis and Reactions. Including Grignard/Organometallic Chem and Redox. |
| Semester-Long Notes | Complete Semester-Long Notes for Printing | |
| Complete Set of Printable Practice Tests for the Semester Answer Keys for the Complete Practice Test Collection |
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| Relevant Test 1 Notes | Pre-Printable Lecture Notes that Were Used in These Test 1 Lecture Movies | |
| 1 | Intro-Syllabus (52 min) (fall) |
1a Overview of Course, Syllabus. (61 min) (Heh heh, syllabus overview was only 13 min in face-to-face course!) 1b Jasperse personal introduction, this one (only) shows the face to go with the voice! :) 1c p1-5. Alcohol Classification and Nomenclature. (35 min) |
| 2 | Alcohols Lecture 2 | p6-9, 15. Organometallics, Grignard Reactions; Drawing Products of Grignard Reactions, Retrosynthetic Analysis. |
| Practice Set 1 Video | General Mechanism Practice/Review and Answers and Video - Video discussing p3 |
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| 3 | Alcohols Lecture 3 (57min) | p10-14. RMgBr Review. Ethylene Oxide (p10) RMgBr Mechanisms,including esters and epoxide (p11-13). Product prediction (p14) |
| Practice Set 2 Video | Mechanisms Problems (Test 1 Specific) and Answers + Video | |
| Quiz1 | Quiz1: Grignard Reactions. Doable now; due by Test 1. (Print, write answers, take picture, and email to Jasperse) | |
| 4 | Alcohols Lecture 4 |
p14-20. More RMgBr Synthetic Analysis, Products (14), Selectivity (12,14), Retrosynthesis (15), Synthesis Design (16). OH C=O incompatible (17). NaBH4 +LiAlH4 Reductions (18-20) |
| 5 | Alcohols Lecture 5 | p18-20, p4-5 NaBH4 +LiAlH4 Reductions. (p18-20) Alcohol reactions. OH Acid-Base(p4-5) |
| Practice Set 3 Video | Acid-Base Practice/Review -- Answers -- Movie | |
| Finish Achieve Ch10 | Finish Achieve Ch10 | |
| 6 | Alcohols Lecture 6 | p6-10. ROH to RONa to ROR; ROH Oxidation; Oxidation-Grignard Combinations |
| 7 | Alcohols Lecture 7 | p10-16 Overview of Oxidation-Reduction chemistry; ROH -> RBr Products + Mech. to RMgBr; Retrosynthesis. |
| Practice Set 4 Video | Retrosynthesis Problems and Answers and Video | |
| 8 | Alcohols Lecture 8 | p16-19 Retrosynthesis, Synthesis Design and Chemical Tests, |
| EU-Intro-Video (25min) | Elements of Unsaturation Notes-- Answers -- Movie (25min) | |
| 9 | Alcohols Lecture 9 | p17-19 Retrosynthesis, Chemical Tests |
| 10 | Alcohols Lect 10 (73 min) |
p19-23 Chemical Tests, Tosylate Chemistry, SOCl2, Mechanisms Practice, Miscellaneous Practice |
| Finish Achieve Ch11 | Finish Achieve Ch11 | |
1. General Mechanism Practice/Review and Answers and Video |
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| Test 1 Preview | ||
| Complete Set of Printable Practice Tests for the Semester Answer Keys for the Complete Practice Test Collection |
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| Practice Test 1-Version 1 + answers + Movie |
Test1v1 and answers, and Movie of Jasperse Going Through it. 52 min | |
| Practice Test 1-Version 2 + answers + Movie |
Test1v2 with answers, and Movie of Jasperse Going Through it. 40 min | |
| Practice Test 1-Version 3 + answers + Movie |
Test1v3 and answers, and Movie of Jasperse Going Through it. 44 min | |
| Practice Test 1-Version 4 + answers + Movie |
Test1v4 and answers, and Movie of Jasperse Going Through it. 42 min | |
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| Test 2 | Test 2 Spectroscopy |
Test 2 Spectroscopy: H-NMR, C-NMR, and IR |
| Relevant NMR notes | Pre-Printable Lecture Notes that Were Used in These NMR Lecture Movies | |
| Relevant NMR Problems |
Pre-Printable NMR Spectra that Were Used in These NMR Lecture Movies | |
| Relevant NMR Answers | Answers to the NMR Spectra that were used in These NMR Lecture Movies | |
| 11 | NMR 1 | Intro to NMR; H-NMR Interpretation |
| EU-Intro-Video (25min) | Elements of Unsaturation Notes-- Answers -- Movie (25min) | |
| 12 | NMR 2 | H-NMR Interpretation |
| Familiar H-NMR Groups | Familiar H-NMR Groups, Easy to Recognize and Video | |
| 13 | NMR 3 | p6-9, 14 NMR3 Overlap, Symmetry, Integration, Splitting, Spectrum Prediction |
| 14 | NMR 4 | p10-14 H-NMRSpectrum Prediction; Chemical Shifts; Practice |
| 15 | NMR 5 | p15- Carbon NMR. |
| 16 | NMR 6 (72 min) | IR, C-NMR Problems, Splitting, Problems |
| Finish Achieve Ch13 | Finish Achieve Ch13 | |
| Familiar H-NMR Groups | Familiar H-NMR Groups, Easy to Recognize and Video | |
| NMR Problems 1-26 | Jasperse practice problems and answers 1-26. Practice problems in the notes that did not get covered in class for reasons of time. |
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| NMR Problems 27-42 | Jasperse practice problems and answers 27-42. | |
| Test 2 Preview | ||
| Complete Set of Printable Practice Tests for the Semester Answer Keys for the Complete Practice Test Collection |
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| Practice Test 2-Version 1 + answers + Movie |
Test2v1 and answers, and Movie of Jasperse Going Through it. 39 min | |
| Practice Test 2-Version 2 + answers + Movie |
Test2v2 with answers, and Movie of Jasperse Going Through it. 38 min | |
| Practice Test 2-Version 3 + answers + Movie |
Test2v3 and answers, and Movie of Jasperse Going Through it. 28 min | |
| Practice Test 2-Version 4 + answers + Movie |
Test2v4 and answers, and Movie of Jasperse Going Through it. 45 min | |
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| Test 3 | Test 3: Carbonyl Chem | Test 3: Carbonyls: Addition Reactions and Enolate Reactions |
| Relevant Carbonyls notes | Pre-Printable Lecture Notes that Were Used in These Carbonly and Enolate Lecture Movies | |
| 17 | Carbonyls Lect 1 | Aldehyde and Ketone Nomenclature. H-Bonding impact on Water Solubility and Boiling Point. Review of Ketone/Aldehyde synthesis reactions we've seen before. |
| 18 | Carbonyls Lect 2 | Carbonyls Synthesis and Mechanisms for Hydrolysis of Enols, Hydrates |
| 19 | Carbonyls Lect 3 | Carbonyl Synthesis; Addition Reactions to Carbonyls |
| 20 | Carbonyls Lect 4 | Reversible Formation of Hydrates and Acetals. Addn/Elim/Substitution Reactions. Protection. |
| Practice Set 1- Movie | Mechanism Practice (Many) Test 3- - - Answers- - -Movie | |
| Quiz2 | Quiz2: Carbonyl Mechanisms, Long. Due by Test 3. ( (Print, write answers, take picture, and email to Jasperse) | |
| 21 | Carbonyls Lect 5 | Acetals, Hemiacetals, Imines, Aminols, Mechanisms |
| Finish Achieve Ch16 | Finish Achieve Ch16 | |
| 22 | Enolates 1 | Aldehyde Oxidation; Chemical Tests; Imines + Mechs; Enolates (Most of class) |
| 23 | Enolates 2 | Enolates Reaction Mechanisms. Proton, Halogen, as Electrophiles |
| 24 | Enolates 3 | p16-22 Halogen Electrophiles; Polysubstitution; Iodoform; LDA vs Ox Bases; Alkyl Halide Electrophiles. |
| Practice Set 1- Movie | Mechanism Practice (Many) Test 3- - - Answers- - -Movie | |
| 25 | Enolates 4 |
LDA, Ox Bases; Mono-carbonyls vs Dicarbonyls; DecarboxEnolate Review, Aldol Reaction/Condensation: Aldehydes/Ketones as Electrophiles |
| 26 | Enolates 5 | More Aldol Reactions. Aldehdyes and Ketones as Electrophiles. |
| Practice Set 1- Movie | Mechanism Practice (Many) Test 3- - - Answers- - -Movie | |
| 27 | Enolates 6 | Claisen: Ester Electrophiles. Wittig Reaction (Phosphorus Ylides) |
| 28 | Enolates 7 | Wittig Reaction and Retrosynthesis/Design |
| Practice Set 2 - Movie | Retrosynthesis Practice Test 3- - - Answers- - -Movie- | |
| Finish Achieve Ch22 | Finish Achieve Ch2 | |
| 1. Mechanism Practice (Many) Test 3- - - Answers- - -Movie 2. Retrosynthesis Practice Test 3- - - Answers- - -Movie Quiz2: Carbonyl Mechanisms, Long. Due by Test 3 |
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| Test 3 Preview | Test Preview | |
| Practice Test 3-Version 1 + answers + Movie |
Test3v1 and answers, and Movie of Jasperse Going Through it. 47 min | |
| Practice Test 3-Version 2 + answers + Movie |
Test3v2 with answers, and Movie of Jasperse Going Through it. 49 min | |
| Practice Test 3-Version 3 + answers + Movie |
Test3v3 and answers, and Movie of Jasperse Going Through it. 45 min | |
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| Test 4 | Test 4: Amines + Acids | Test 4: Amines, Carboxylic Acids, Esters, and Amides |
| Relevant Notes | Pre-Printable Lecture Notes that Were Used in These Amines and Acids Lecture Movies | |
| 29 | Amines Lect 1 | Amines 1. Nomenclature, Hybridization. Begins at 26 min into video. |
| Practice Set 1- Movie | Acid-Base Practice/Review/Basics (Easy) -- Answers -- Movie | |
| 30 | Amines Lect 2 | Amines 2. Properties, Basicity. Hybridization of N-lone pairs; Reactivity of Amines; Acid-Base Chemistry |
| 31 | Amines Lect 3 | Amines 3. Amine/Ammonium acid/base chemistry. |
| Practice Set 2- Movie | Acid-Base Practice (Harder, Test Oriented) -- Answers -- Movie -- Pod | |
| 32 | Amines Lect 4 | Amines 4. Acid-Base. Alkylation/Polyalkylation of Amines. |
| 33 | Amines Lect 5 | Alkylation and Amidation of Amines. Synthesis/Synthesis Design/Retrosynthesis of Amines. |
| 34 | Amines6-Acids1 |
Amines 6: p32-37, 1-32min. Amine Synthesis and Synthetic Design |
| Finish Achieve Ch19 | Finish Achieve Ch19 | |
| 35 | Acids Lecture 2 |
Acids 2. p12-19. AcidityAcid Synthesis.Hydrolysis of Acid chlorides, anhydrides, esters, and amides |
| 36 | Acids Lecture 3 | Acids 3. p20-25 Reactions of Acids. SOCl2, conversion to ClAvEN-O |
| Practice Set 3- Movie | Mechanisms, Retrosynthesis + Synthesis Design --- Answers --- Movie | |
| 37 | Acids Lecture 4 |
Acids 4. p26-30 ClAvEN-O interconversions, including uphill. Acid Chlorides, Anhydrides, Esters, and Amides. Synthetic interconversion. |
| 38 | Acid Lecture 5 | Acids 5. p30-36 Practice Problems in manual. |
| 39 | Polymers Lecture (31-min) |
Polymers Chemistry. Not Test responsible. |
| 1. Acid-Base Practice (Easy) -- Answers -- Movie 2. Acid-Base Practice (Less Easy) -- Answers -- Movie 3. Mechanisms, Retrosynthesis + Synthesis Design --- Answers --- Movie |
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| Test 4 Preview | 2-minute overview of what Test 4 will look like. | |
| Practice Test 4-Version 1 + answers + Movie |
Test4v1 and answers, and Movie of Jasperse Going Through it. 47 min | |
| Practice Test 4-Version 2 + answers + Movie |
Test4v2 with answers, and Movie of Jasperse Going Through it. 49 min | |
| Practice Test 4-Version 3 + answers + Movie |
Test4v3 and answers, and Movie of Jasperse Going Through it. 47 min | |
| FINAL | Final Exam Preview |
Final Exam Preview: Note: Final used fall and spring, but NOT SUMMER |
| Final Exam-Version 1 + answers + Movie |
Final-Exam-v1 and answers, and Movie of Jasperse Going Through it. 55 min. -Note: on certain pages, especially page 6, the actual final won't have as many problems |
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