Minnesota State University Moorhead
Dr. Craig P. Jasperse, Chemistry
email: jasperse@mnstate.edu   Phone: (218) 477-2230   Office: Hagen 407J                             

Online Organic
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Chem 350 Lectures 2013
1. These lectures, recorded during my Organic Chemistry lectures at MSUM, are roughly 50 minutes in length.
2. To see the pre-printable lecture notes used in these lectures, see the "complete class notes" or the relevant notes
linked beneath each Test listing. The preprintable practice tests are available from the Chem350 Practice Tests Link.
3. Recorded lectures from last fall's Chem350 class are available and cover almost identical notes, if you know you're going to miss a class.
On this website, a link from tomorrow or a future day are links to last year's lectures on the equivalent days. (Usually they are fairly close, but may be
sometimes a bit ahead or a bit behind.) "Last year's" lectures will be replaced by "this year's" lectures ASAP after class is completed.
4 . Recorded lectures from this summer's Chem341 class are also available and cover almost identical notes, if you know you're going to miss a class
5. If you have trouble, contact Dr. Jasperse for help.

      Movies mp4 Files Topic
      Test 1 Intro and Alkanes.   Test 1 Intro and Alkanes
    Date Relevant Test 1notes   Pre-Printable Lecture Notes that Were Used in These Test 1 Lecture Movies
1 M 8/26 Intro + Syllabus IntroPod Class Introduction, Syllabus, Etc.
1 M 8/26 OChem -Intro Lecture 1 Pod-1 (Real Notes.) Why Carbon is Special, Normal bonding, Lewis Structures in Organic
2 W

8/28

 OChem-Intro Lecture 2 Pod-2

1. Formal Charge and Abnormal Bonding. 2. Structural formulas: Full, Condensed, and Skeletal
3 F 8/30 OChem -Intro Lecture 3 Pod-3 1. Resonance Structures 2. Arrow-Pushing to Track Electrons
4 W 9/4 OChem -Intro Lecture 4 Pod-4 Mechanism/Arrow-pushing. Acid-Base Chemistry.
5 F 9/6 OChem -Intro Lecture 5 Pod-5 Anion Stability Patterns. VSEPR 3D Shape; Drawing 3D; Hybridization; Pi bonds; Isomers
6 M 9/9 OChem -Intro Lecture 6 Pod-6 Polarity, IMF, Boiling Points, Solubility. Functional Groups
7 W 9/11 OChem -Intro Lecture 7 Pod-7

Functional Groups. Alkanes: structure, formulas, properties, and nomenclature.
8 F 9/13 OChem -Alkanes Lect 8 Pod-8 Nomenclature, Newman Projections for Conformations of Acyclic Alkanes
9 M 9/16 OChem -Alkanes Lect 9 Pod-9 Newman Projections; Torsional and Steric Strain; Cycloalkanes and Nomenclature
10 W 9/18

OChem -Alkanes Lecture 10a
(from 31:00 on)
Chem -Alkanes Lecture 10b
(0-35:00)

Pod-A
(from 31)
Pod-B
(to 35)

Cyclohexane Chairs, Cis-and-Trans, Structural Isomers.
      Test1Preview    
      Practice Test 1-Version 1   Tegrity Movie of Jasperse Going Through it
      Practice Test 1-Version 2 Pod1v2 Regular Panopto Movie of Jasperse Going Through it. 49 min
      Practice Test 1-Version 3   Tegrity Movie of Jasperse Going Through it
      Practice Test 1-Version 4 Pod1v4 Regular Panopto Movie of Jasperse Going Through it. 33 min
      Test 2 Radical Halogenation,
Basic Principles of Reactivity,
Stereochemistry, SN2/SN1/E2/E1 		  Test 2 Radical Halogenation, Basic Principles of Reactivity,
Stereochemistry, and SN2/SN1/E2/E1 reactions of Alkyl Halides
      Relevant Test 2notes   Pre-Printable Lecture Notes that Were Used in These Test 2 Lecture Movies
11 M 9/23 OChem -Reactions Lecture 1 Pod-11 Radical Halogenation; Mechanism; Radicals; Bond Energies; Reaction Energies
12 W 9/25 OChem-Reactions Lecture 2 Pod-12 Rate Laws, Transition States, Stability-Reactivity Principles
13 F 9/27 OChem -Reactions Lecture 3 Pod-13

Radical Brominations. Major product, mechanism, structure isomers. Stability patterns for carbon radicals, cations, and anions.

14a M 9/30 OChem -Reactions Lecture 4 Pod-14a

17 min. Radical bromination and mechanism practice. Stability-Reactivity-Selectivity Principle. Why Radical Brominationis more Selective than Chlorination. Overview of stability-reactivity principles.

14b M 9/30 OChem -Stereo Lecture 1 Pod-14b 32 min. Chiral vs achiral, Enantiomers, Recognizing/Drawing Mirror Images.
15 W 10/2 OChem - Stereo Lecture 2 Pod-15

Chiral Carbons; Attachment Priorities; R/S Designation; Drawing Chiral Molecules
16 F 10/4 OChem - Stereo Lecture 3 Pod-16 Racemic MIxtures, Optical Activity, Meso, Molecules with More than One Chiral Center
17 M 10/7 OChem - Stereo Lecture 4/RX 1 Pod-17 Drawing Stereoisomers, Meso Compounds. Alkyl Halides Intro, Classification, and Naming
First 27 min finish Ch 5, last 22 minutes start Ch 6.
18 W 10/9 OChem -Sn-E Lecture 2 Pod-18 SN2 Reaction. Product Prediction, Structural Factors.
Tech failure, this is copy from previous year. Minutes 6-10 are redundant from previous lecture, otherwise good.
19 F 10/11 OChem -Sn-E Lecture 3 Pod-19 SN2 Reactions in MOre Depth; SN1 reactions started.
20 W 10/16 OChem -Sn-E Lecture 4 Pod-20 SN1 REactions in More Depth. Elimination Reactions
Note: Audio error, very soft. Will need headphones and volume turned up.
21 F 10/18 OChem -Sn-E Lecture 5 Pod-21 E1 and E2 Reactions in More Depth; Recognizing Which Reaction Will Occur
      Practice Problems Undone in Class Pod-21-B Practice Problems in Notes that went Uncovered in Class
22a M 10/21 OChem -Sn-E Lecture 5a Pod-22-A Technical Problems. This video is copy from 2012, but is good.
11 minutes, touching on some Test-Style problems. And an SN1 or E1
      Extra Mechanism Practice Problems Pod-21-C Extra Mechanism and Product Prediction Problems
      Extra Stereochem Practice Problems Pod Extra R/S, Chiral vs Achiral, and Same/Enantiomer/Diastereomer Practice Problems
      Extra Radical Bromination Practice Pod Extra Br2/hv Product Prediction and Mechanism Practice Problems
      Test 2 Preview   Test 2 Preview - 6 minutes
      Practice Test 2-Version 1   Practice Test 2-Version 1-Movie of Jasperse Going Through it
      Practice Test 2-Version 2   Practice Test 2-Version 2-Movie of Jasperse Going Through it
      Practice Test 2-Version 3 Pod2v3 Regular Panopto Movie of Jasperse Going Through it. 34 min
    Practice Test 2-Version 4 Pod2v4 Regular Panopto Movie of Jasperse Going Through it. 28 min
      Test 3: ALKENES   Test 3: Alkenes. Properties, Synthesis, Reactions
      Relevant Test 3 notes   Pre-Printable Lecture Notes that Were Used in These Test 3 Lecture Movies
22 M 10/21 OChem Alkenes Lecture 1 Pod-22b 29-min Partial lecture. Intro to alkenes, Elements of Unsaturation (EU), Hydrogenation
23 F 10/25 OChem Alkenes Lecture 2 Pod-23 Alkene Nomenclature; E/Z stereochem; Bulky Bases for Hofmann Elimination
24 M 10/28 OChem Alkenes Lecture 3 Pod-24 Alkene Formation from RX (Bulky vs Normal Base) and From Alcohols via Acid-Catalyzed E1
25 W 10/30 OChem Alkenes Lecture 4 Pod-25 Mechanism Recognition Addition reactions to Alkenes
26 F 11/1 OChem Alkenes Lecture 5 Pod-26 Addition of HBr; Acid-Catalyzed HOH Addn; Oxymercuration/Demercuration; Anti-Markovnikov Hydroboration-Oxidation
27 M 11/4 OChem Alkenes Lecture 6 Pod-27 Synthesis Design, anti-Mark HBr addition; H2 addn; synthesis design; pi complexes
28 W 11/6 OChem Alkenes Lecture 7 Pod-28 Br2 and BrOH additions and mechanisms; epoxidation
29 F 11/8 OChem Alkenes Lecture 8 Pod-29 Dihydroxylation, Ozonolysis. Stereospecific Alkene Reactions. Synthetic Design.
Due to technical issues, this is actually the 2012 lecture, but covers almost exactly the
same notes as discussed in the actual 2013 lecture.
29b F 11/8 OChem Alkenes p 31-33 (30 min) Pod-29b Coverage of p31-33 in notes, that weren't done in class.
      Test 3 Extra Synthesis Design Pod-29c Discussion of some Extra Synthesis Design Problems
      Test 3 Preview Pod Test preview
      Practice Test 3 V1   Practice Test 3-Version 1-Movie of Jasperse Going Through it (Tegrity movie)
      Practice Test 3 V2   Practice Test 3-Version 2-Movie of Jasperse Going Through it (Tegrity movie)
      Practice Test 3 V3 Pod3v3 Practice Test 3-Version 3-Movie of Jasperse Going Through it. 36 min
      Practice Test 3 V4 Pod3v4 Practice Test 3-Version 4-Movie of Jasperse Going Through it. 33 min
      Test 4: Conjugation and Aromatics   Conjugation, Aromatics, and Reactions of Aromatics
      Relevant Test 4 Notes   Pre-Printable Lecture Notes that Were Used in These Test 4 Lecture Movies
30 M 11/11 OChem Conjugation Lecture 1 Pod-30 Conjugation: Introduction, impact on stability, reactivity, hybridization, lone-pairs. Dienes. Conjugation materials begins at 15 minutes in.
31 F 11/15 OChem Conjugation Lecture 2 Pod-31

Conjugated Dienes, allylic cations. Asymmetric allylic cations can give Two Products.
This is 2012 lecture; technical problem in 2013. New material starts at 12 minutes.

32 M 11/18 OChem Conjugation Lecture 3 Pod-32 1,2 + 1,4 Addn to Conjugated Dienes. NBS allylic halogenation. Allylic anions.
      HBr to Dienes, Allylic Bromination Pod HBr Addition to Dienes and NBS Allylic Bromination Practice Answers Movie
33 W 11/20 Diels Alder Lecture Pod-33 Diels-Alder Reactions of Conjugated Dienes
34 F 11/21 OChem Aromatics Lecture 1
 Pod-34 Diels Alder Wrapup. Aromaticity,Frost Diagrams, Huckel's Rule
35 M 11/25

OChem Aromatics Lecture 2 and intro to Aromatic Reactions

 Pod-35

Aromatic Heterocycles, Ions; Nitrogen lone-pair hybridization and basicity;
Aromatic Nomenclature. Intro to Electrophilic Aromatic Substitution Reactions
36 M 12/1 OChem Aromatics Substitution 1 Pod-36 p5-11 Aromatic Substitution Reactions. Mechanisms and Electronics. Halogenation.
37 W 12/3 OChem Aromatics Substitution 2 Pod-37 p11-17 Aromatic SubstitutinSubstituent Directing StrengthAromatic Nitration, Alkylation, Acylation, Addition to Disubbed Benzenes
38 F 12/5 OChem Aromatics Substitition 3 Pod-38 p17-21 Aromatic Substitution. Synthesis Design. Protection-Deprotection. Side chain oxidation/bromination. Synthesis Design.
      Test4Preview Pod  
     

Aromatic Substitution Mechanisms

 Pod Aromatic Substitution Mechanisms (Products Provided) and Answers
      Aromatic Product Prediction/ Mechanisms/Synthesis Design Pod Aromatic Substitution Product Prediction/Mechanisms/Synthesis Design Practice and Answers
      Practice Test 4-Version 1 Pod4v1 Regular Panopto Movie of Jasperse Going Through it. 50 min
      Practice Test 4-Version 2 Pod4v2 Regular Panopto Movie of Jasperse Going Through it. 42 min
      Practice Test 4-Version 3 Pod4v3 Regular Panopto Movie of Jasperse Going Through it. 50 min
           
      Final Exam Practice Tests    
      Final Exam Preview Pod http://coursecast.mnstate.edu/Panopto/Pages/Viewer/Default.aspx?id=08bb7459-cd50-48c1-b676-ab0de2f20a5e
      Final Exam Practice Version 1   http://coursecast.mnstate.edu/Panopto/Pages/Viewer/Default.aspx?id=c29cb1a9-390b-4ccb-ba8e-b3a28c01cd8e
Note: this is a regular web link, not a Quicktime link. Double click on the view screen to get a full-screen look.
      Final Exam Practice Version 2   http://coursecast.mnstate.edu/Panopto/Pages/Viewer/Default.aspx?id=19ceaa38-d52b-42fc-be8c-b21eb910a6d6
Note: this is a regular web link, not a Quicktime link. Double click on the view screen to get a full-screen look.