Dr. Craig P. Jasperse, Chemistry
email: jasperse@mnstate.edu Phone: (218) 477-2230 Office: Hagen 407J
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Minnesota State University Moorhead
Dr. Craig P. Jasperse, Chemistry email: jasperse@mnstate.edu Phone: (218) 477-2230 Office: Hagen 407J |
Online Organic
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Organic Chemistry I Chem 350online Lectures
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| Movies | mp4 Files | Sapling | Topic | |||
| Test 1 Intro and Alkanes. | Test 1 Intro and Alkanes | |||||
| Date | Relevant Test 1notes | Pre-Printable Lecture Notes that Were Used in These Test 1 Lecture Movies | ||||
| Lecture 1 and 2 actually 2016, tech problems 2017 | ||||||
| 1 | M | 8/21 | Intro + Syllabus + p1 | IntroPod | training sessions |
Class Introduction, Syllabus, Etc. (Real Notes.) p1 Why Carbon is Special, Bonding Basics (p1) |
| 2 | W | 8/23 |
OChem-Intro Lecture 2 | Pod-2 | 1:1-7 |
p2-4,6. 1. Normal Bonding. 2. Formal Charge and Abnormal Bonding. 3. Electronegativity |
| Lectures 3 and on updated with 2017 videos after they happen. (Usually within 0-3 days) | ||||||
| 3 | F | 8/25 | OChem -Intro Lecture 3 | Pod-3 | 1:8-21 | 1. Structural formulas: Full, Condensed, and Skeletal 2. Resonance Structures 3. Arrow Pushing |
| Extra Resonance Video | Extra Resonance Video (ChemSurvival, 6 min) | |||||
| Arrow-pushing and Podcast | Mechanistic Arrow-Pushing Problems and Answers, 29-min Movie Linked to the Left | |||||
| 4 | M | 8/28 | OChem -Intro Lecture 4 | Pod-4 | 1:22-27 | 1. Mechanism/Arrow-pushing. 2. Resonance 3. Acid-Base Chemistry. 4. Anion Stability Patterns. |
| Extra Acid-Base Video and Pod | Extra Acid Base Problems and Answers, 36-min Movie Linked to the Left | |||||
| 5 | W | 8/30 | OChem -Intro Lecture 5 | Pod-5 | Acid-Base Chemistry. Anion Stability Patterns. VSEPR 3D Shape. Drawing 3D. | |
| 3-D Structure Drawing and Podcast | Extra 3-D Structure-Drawing Problems and Answers, 45-min Movie Linked to the Left | |||||
| top | Extra VSEPR Video 1. (4 min) Extra VSEPR Video 2 (Jasperse, 6 min) |
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| 6 | F | 9/1 | OChem -Intro Lecture 6 | Pod-6 | 2:1-14 | Drawing 3D; Hybridization; Pi bonds; Isomers |
| 7 | W | 9/6 | OChem -Intro Lecture 7 | Pod-7 | 2:15-18 | Polarity IMF, Boiling Points; Solubility. Functional Groups. |
| 8 | F | 9/8 | OChem -Alkanes Lect 8 | Pod-8 | 2:15-18 3:1-10 |
p9-p3 Functional Groups. Alkane Nomenclature. |
| Newman Practice Movie and Pod | Extra Newman Practice Problems and Answers | |||||
| Extra Newman Video 1 (ethane) Extra Newman Video 2 (ethane) Extra Newman Video 3 (butane) |
Extra Newman Video 1 (ChemSurvival, ethane, 3 min) Extra Newman Video 2 (ChemSurvival, ethane, 5 min) Extra Newman Video 3 (ChemSurvival, butane, 6 min) |
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| 9 | M | 9/11 | OChem -Alkanes Lect 9 | Pod-9 | 3:11-22 | p2-8 Newman Projections, Cycloalkanes |
| Cyclohexane Movie and Pod | Extra Cycloehxane Chair Practice Problems and Answers Cyclohexane and Newman Projections Summary |
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| Cyclohexane chairs and chair flips Substituted Cyclohexanes |
Extra Chair Video 1: Cyclohexane (ChemSurvival, 3 min) Extra Chair Video 2: Substituted Cyclohexane (ChemSurvival, 4 min) |
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| 10 | W | 9/13 | OChem -Alkanes Lect 10 | Pod-10 | 3:23-29 | p7-11 Cyclohexane Chairs, Cis-and-Trans, Structural Isomers. |
| Test 1 Preview and Practice Tests | ||||||
| Test1Preview | ||||||
| Practice Test 1-Version 1 | Tegrity Movie of Jasperse Going Through it | |||||
| Practice Test 1-Version 2 | Pod1v2 | Regular Panopto Movie of Jasperse Going Through it. 49 min | ||||
| Practice Test 1-Version 3 | Tegrity Movie of Jasperse Going Through it | |||||
| Practice Test 1-Version 4 | Pod1v4 | Regular Panopto Movie of Jasperse Going Through it. 33 min | ||||
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| Test 2 Radical Halogenation, Basic Principles of Reactivity, Stereochemistry, SN2/SN1/E2/E1 |
Test 2 Radical Halogenation, Basic Principles of Reactivity, Stereochemistry, and SN2/SN1/E2/E1 reactions of Alkyl Halides |
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| Relevant Test 2notes | Pre-Printable Lecture Notes that Were Used in These Test 2 Lecture Movies | |||||
| 11 | F | 9/15 | OChem-Reactions Lecture 1 | Pod-11 | 4:1-5 | p1-7 Radical Halogenation Mech; Bond Strengths; Radical Stabilities; |
| 12 | W | 9/20 | OChem -Reactions Lecture 2 | Pod-12 | 4:6 | p7-11 Rate Laws, Transition States, Stability-Reactivity Principles. Radical Brominations. Major product, mechanism, structural isomers. |
| 13 | F | 9/22 | OChem -Reactions Lecture 3 |
Pod-13 | 4:7-14 | p11-18 Radical Brominations. Product, mechanism. Stability patterns for radicals/cations/anions. Stability-reactivity principles. |
| Radical Practice Video | Pod | Br2/hv Products/Mechanisms Practice and Answers | ||||
| 14 |
M | 9/25 | Stereo Lecture 1 -Stereo starts at 16:40 |
5:1-5 | p1-3 , Chiral Carbons; Chiral vs achiral; Same vs Enantiomers; Attachment Priorities; R/S Designation | |
| Stereochem Practice Video | Pod | Stereochem Practice and Answers (video is a little slow to load, be patient at start) | ||||
| 15 | W | 9/27 | OChem - Stereo Lecture 2 | Pod-15 | 6-16 | p3-5 Chiral Carbons; Attachment Priorities; R/S Designation; Drawing Chiral Molecules. |
| Stereochem Practice Video | Pod | Stereochem Practice and Answers (video is a little slow to load, be patient at start) | ||||
| 16 | F | 9/29 | OChem - Stereo Lecture 3 | Pod-16 | 17-28 | p4-10 Racemic mixtures and Optical Activity. Conformations + Chirality; Planes of Symmetry; Meso; Cis/Trans Diastereomers vs Enantiomers; Recognizing Chiral vs Meso |
| Stereochem Practice Video | Pod | Stereochem Practice and Answers (video is a little slow to load, be patient at start) | ||||
| 17 | M | 10/2 | Stereo-4 RX-Sn-E Lecture 1 | Pod-17 | 6:1-5 | p10-11 Stereo (1-19min) p1-6 Alkyl Halides. Reaction preview; Alkyl/Vinyl/Aryl/Allyl Classification; 1º/2º/3º Classification; overview of SN2/SN1/E2/E1 reactions; SN2 reactions and mechanism |
| 18 | W | 10/4 | OChem -Sn-E Lecture 2 | Pod-18 | 6:6-17 | p6-10 SN2 Reaction. Product Prediction, Structural Factors. Ranking. Inversion. Mechanisms. |
| 19 | F | 10/6 | OChem -Sn-E Lecture 3 | Pod-19 | 6:18-26 | p11-15 SN1 Reactions. |
| 20 | M | 10/9 | OChem -Sn-E Lecture 4 | Pod-20 | 6:27-31 | p16-23. E1, E2 Reactions. Zaytsev's Rule. Using Anion/Neutral and 1º, 2º, 3º to diagnose among SN2/E2/SN1/E1 |
| 21 | W | 10/11 | OChem -Sn-E Lecture 5 Notes p 25 and 27 not done in class |
Pod-21 Pod-21b |
6:32-41 | 67 minutes. p21,23-29. Including p 25 (mechanisms) and 27 (product prediction) not done in class. E2 Stereochemistry; Diagnosing Reaction Types; Two-Step Synthesis Design; E1 + E2 Mechanisms; Ranking Problems |
| Extra Mechanism Practice Problems | Pod-21-C | Extra Mechanism and Product Prediction Problems | ||||
| Extra Stereochem Practice Problems | Pod | Extra R/S, Chiral vs Achiral, and Same/Enantiomer/Diastereomer Practice Problems | ||||
| Extra Radical Bromination Practice | Pod | Extra Br2/hv Product Prediction and Mechanism Practice Problems | ||||
| Test 2 Preview | Test 2 Preview - 6 minutes | |||||
| Practice Test 2-Version 1 | Practice Test 2-Version 1-Movie of Jasperse Going Through it | |||||
| Practice Test 2-Version 2 | Practice Test 2-Version 2-Movie of Jasperse Going Through it | |||||
| Practice Test 2-Version 3 | Pod2v3 | Regular Panopto Movie of Jasperse Going Through it. 34 min | ||||
| Practice Test 2-Version 4 | Pod2v4 | Regular Panopto Movie of Jasperse Going Through it. 28 min | ||||
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| Test 3: ALKENES | Test 3: Alkenes. Properties, Synthesis, Reactions | |||||
| Relevant Test 3 notes | Pre-Printable Lecture Notes that Were Used in These Test 3 Lecture Movies | |||||
| 22 | M | 10/16 | OChem Alkenes Lecture 1 (44 minutes long) |
Pod-22 | 7:1-11 | Nonreactive "Strong acid" anions. p1-5. Intro to alkenes, (EU), Hydrogenation; Alkene Nomenclature; E/Z stereochem |
| 23 | W | 10/18 | OChem Alkenes Lecture 2 (58 minutes long) |
Pod-23 | 7:12-23 | p5-11 Alkene Stabilities; Heats of Hydrogenation/Combustion; Bulky Bases/Normal Bases for Hofmann/Zaytsev Elimination |
| 24 | F | 10/20 | OChem Alkenes Lecture 3 | Pod-24 | 7:18-25 | p12-16 Alkene Formation. From Alcohols via Acid-Catalyzed E1. Mechanism Recognition. |
| 25 | M | 10/23 | OChem Alkenes Reactions 1 |
Pod-25 | 8:1-9 | p1-13; Overview, Intro, Addition reactions to Alkenes. Addition of (Markovnickov and Anti-Markovnikov); Acid-Catalyzed HOH Addn; |
| 26 | W | 10/25 | OChem Alkenes Reactions 2 | Pod-26 | 8:10-18 | p13-18 Acid-Catalyzed HOH Addn; Oxymercuration/Demercuration; Anti-Markovnikov Hydroboration-Oxidation |
| 27 | F | 10/27 | OChem Alkenes Reactions 3 | Pod-27 | 8:19-21 | 19-23 Synthesis Design, H2 addn; Br2 addn |
| 28 | M | 10/30 | OChem Alkenes Reactions 4 |
Pod-28 | 8:22-36 | 23-28 Br2 and Br2/H2O additions and mechanisms; epoxidation; Cis and Trans Dihydroxylation; Stereospecific Rxns |
| 29 | W | 11/1 | OChem Alkenes Reactions 5 (56 minutes long) Extra Session, Page 33 (6 min) |
Pod-29 Pod-29b |
8:35-41 | p28-33. Dihydroxylation, Ozonolysis. Stereospecific Alkene Reactions. Synthetic Design. |
| Test 3 Extra Synthesis Design Practice | Pod | Discussion of Extra Synthesis Design Practice Problems | ||||
| Test 3 Preview | Pod | Test preview | ||||
| Practice Test 3 V1 | Pod3v1 | Practice Test 3-Version 1-Movie of Jasperse Going Through it (Tegrity movie) | ||||
| Practice Test 3 V2 | Pod3v2 | Practice Test 3-Version 2-Movie of Jasperse Going Through it (Tegrity movie) | ||||
| Practice Test 3 V3 | Pod3v3 | Practice Test 3-Version 3-Movie of Jasperse Going Through it. 36 min | ||||
| Practice Test 3 V4 | Pod3v4 | Practice Test 3-Version 4-Movie of Jasperse Going Through it. 33 min | ||||
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| Test 4: Conjugation and Aromatics | Conjugation, Aromatics, and Reactions of Aromatics | |||||
| Relevant Test 4 Notes | Pre-Printable Lecture Notes that Were Used in These Test 4 Lecture Movies | |||||
| 30 | F | 11/3 | OChem Conjugation Lecture 1 |
Pod-30 | p1-6 Conjugation: Introduction, impact on stability, reactivity, hybridization, lone-pairs. Conjugated Dienes, allylic cations. 37 min. |
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| 31 | W | 11/8 | OChem Conjugation Lecture 2 | Pod-31 | 15:1-9 | p6-10 Asymmetric allylic cations can give Two Products. 1,2/1,4-Addn to Dienes. |
| 32 | M | 11/13 | OChem Conjugation Lecture 3 | Pod-32 | 15:10-13 | p10-17. Allylic Cations. Allylic Radicals (NBS bromination). Allylic anions. Allylic SN2. Diels-Alder Intro. (p15,16 skip) |
| HBr to Dienes, Allylic Bromination | Pod | HBr Addition to Dienes and NBS Allylic Bromination Practice Answers Movie | ||||
| 33 | W | 11/15 | Diels Alder Lecture | Pod-33 | 15:14-20 | p17-21. Diels-Alder Reactions of Conjugated Dienes. (p22-25 skip) |
| 34 | F | 11/17 | 2015 OChem Aromatics Lecture 1 2016 Version: Aromatics 1 |
Pod-34 2016 Pod |
16:1-12 | p1-6 Aromaticity,Frost Diagrams,Huckel's Rule,Ions,Heterocycles,N lone-pair hybridization and basicity |
| 35 | M | 11/20 | 2015 OChem Aromatics Lecture 2 and intro to Aromatic Reactions |
Pod-35 2016Pod |
16:13-19 |
p6-8 Nitrogen lone-pair hybridization and basicity; Aromatic Nomenclature. |
| 36 | M | 11/27 | 2015 OChem Aromatics Substitution 2 2016 Version: Aromatics Substitution 2 |
Pod-36 2016Pod |
17:1-21 | p6-11 Aromatic Substitution Reactions. Mechanisms and Electronics. Halogenation. |
| 37 | W | 11/29 | 2015 OChem Aromatics Substitution 3 2016 Version: Aromatics Substitution 3 |
Pod-37 2016Pod |
p12-17 Aromatic SubstitutinSubstituent Directing StrengthAromatic Nitration, Alkylation, Acylation, Addition to Disubbed Benzenes | |
| 38 | F | 12/1 | 2015 OChem Aromatics Substitition 4 2016 Version: Aromatics Substitution 4 |
Pod-38 2016Pod |
p17-21 Aromatic Substitution. Synthesis Design. Protection-Deprotection. Side chain oxidation/bromination. Synthesis Design. | |
| Test4Preview | Pod | |||||
| Pod | Aromatic Substitution Mechanisms (Products Provided) and Answers | |||||
| Aromatic Product Prediction/ Mechanisms/Synthesis Design | Pod | Aromatic Substitution Product Prediction/Mechanisms/Synthesis Design Practice and Answers | ||||
| Practice Test 4-Version 1 | Pod4v1 | Regular Panopto Movie of Jasperse Going Through it. 50 min | ||||
| Practice Test 4-Version 2 | Pod4v2 | Regular Panopto Movie of Jasperse Going Through it. 42 min | ||||
| Practice Test 4-Version 3 | Pod4v3 | Regular Panopto Movie of Jasperse Going Through it. 50 min | ||||
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| Final Exam Practice Tests | ||||||
| Final Exam Preview | Pod | http://coursecast.mnstate.edu/Panopto/Pages/Viewer/Default.aspx?id=08bb7459-cd50-48c1-b676-ab0de2f20a5e | ||||
| Final Exam Practice Version 1 | http://coursecast.mnstate.edu/Panopto/Pages/Viewer/Default.aspx?id=c29cb1a9-390b-4ccb-ba8e-b3a28c01cd8e Note: this is a regular web link, not a Quicktime link. Double click on the view screen to get a full-screen look. |
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| Final Exam Practice Version 2 | http://coursecast.mnstate.edu/Panopto/Pages/Viewer/Default.aspx?id=19ceaa38-d52b-42fc-be8c-b21eb910a6d6 Note: this is a regular web link, not a Quicktime link. Double click on the view screen to get a full-screen look. |
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