Dr. Craig P. Jasperse, Chemistry
email: jasperse@mnstate.edu Phone: (218) 477-2230 Office: Hagen 407J
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Minnesota State University Moorhead
Dr. Craig P. Jasperse, Chemistry email: jasperse@mnstate.edu Phone: (218) 477-2230 Office: Hagen 407J |
Online Organic
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Organic Chemistry I Chem 350online Lectures
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| Movies | Sapling | Topic | |||
| Test 1 Intro and Alkanes. | Test 1 Intro and Alkanes | ||||
| Date | Relevant Test 1notes | Pre-Printable Lecture Notes that Were Used in These Test 1 Lecture Movies | |||
| 1 | M | 8/26 | Intro + Syllabus (50 min) Jasperse face-voice intro (13 min) OChem-Intro Lecture 1 (13min) |
training sessions |
Class Introduction, Syllabus, Etc. (Real Notes.) p1 Why Carbon is Special, Bonding Basics (p1) |
| 2 | W | 8/28 |
OChem-Intro Lecture 2 | 1:1-7 |
p2-4,6. 1. Normal Bonding. 2. Formal Charge and Abnormal Bonding. 3. Electronegativity |
| 3 | F | 8/30 | OChem-Intro Lecture 3 | 1:8-21 | 1. Structural formulas: Full, Condensed, and Skeletal 2. Resonance Structures 3. Arrow Pushing |
| Extra Resonance Video | Extra Resonance Video (ChemSurvival, 6 min) | ||||
| Mechanistic Arrow-Pushing Problems Arrow-pushing video |
Mechanistic Arrow-Pushing Problems and Answers, 29-min Movie | ||||
| 4 | W | 9/4 | OChem -Intro Lecture 4 | 1:22-27 | 1. Resonance Wrapup 2. Mechanism/Arrow-pushing. |
| Extra Acid Base Problems Acid-Base Video |
Extra Acid Base Problems and Answers, 36-min Movie | ||||
| 5 | F | 9/6 | OChem -Intro Lecture 5 -2018 video. 2019 audio failed. |
Acid-Base Chemistry. Anion Stability Patterns. VSEPR 3D Shape. Drawing 3D. | |
| 3-D Structure-Drawing Problems 3-D Drawing Video |
Extra 3-D Structure-Drawing Problems and Answers, 45-min Movie | ||||
| top | Extra VSEPR Video 1. (4 min) Extra VSEPR Video 2 (Jasperse, 6 min) |
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| Quiz 1 Ch 1 (Required) | Quiz 1 Ch 1 (Required. Can just email letter answers to Jasperse) | ||||
| 6 | M | 9/9 | OChem -Intro Lecture 6 | 2:1-14 | Drawing 3D; Hybridization; Pi bonds; Isomers |
| Isomers Practice PDF + Answers Isomers Video |
Extra Isomers Practice and Answers, 36-min Movie Linked to the Left | ||||
| 7 | W | 9/11 | OChem -Intro Lecture 7 | 2:15-18 | Isomers; Polarity IMF, Boiling Points; Solubility. Functional Groups. |
| Quiz 2 Ch 2 (Required) | Quiz 2 Ch 2 (Required, email letter answers to Jasperse sometime prior to Test 1)) | ||||
| 8 | F | 9/13 | OChem -Alkanes Lect 8 | 2:15-18 3:1-10 |
p9-p3 Functional Groups. Alkane Nomenclature. |
| Newman Practice Problems Newman Practice Movie |
Extra Newman Practice Problems and Answers and Movie | ||||
| Extra Newman Video 1 (ethane) Extra Newman Video 2 (ethane) Extra Newman Video 3 (butane) |
Extra Newman Video 1 (ChemSurvival, ethane, 3 min) Extra Newman Video 2 (ChemSurvival, ethane, 5 min) Extra Newman Video 3 (ChemSurvival, butane, 6 min) |
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| 9 | M | 9/16 | OChem -Alkanes Lect 9 | 3:11-22 | p2-8 Newman Projections, Cycloalkanes |
| Cyclohexane Chair Problems Cyclohexane Movie |
Extra Cycloehxane Chair Practice Problems and Answers and Movie Cyclohexane and Newman Projections Summary |
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| Cyclohexane chair video Substituted Cyclohexane Video |
Extra Chair Video 1: Cyclohexane (ChemSurvival, 3 min) Extra Chair Video 2: Substituted Cyclohexane (ChemSurvival, 4 min) |
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| 10 | W | 9/18 | OChem -Alkanes Lect 10 (63min) |
3:23-29 | p7-11 Cyclohexane Chairs, Cis-and-Trans, Structural Isomers. |
1. PS#1: Mechanistic Arrow-Pushing Problems and Answers, and Movie |
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| Test 1 Checklist PDF | Print This Checklist. Am I missing anything? | ||||
| Test 1 Skills/Competencies | Can I do all of this? | ||||
| Test 1 Preview and Practice Tests | |||||
| Test1Preview | |||||
| Practice Test 1-Version 1 + answers + Movie |
Test1v1 and answers, and explanatory Movie of Jasperse Going Through it | ||||
| Practice Test 1-Version 2 + answers + Movie |
Test1v2 and answers, and explanatory Movie of Jasperse Going Through it. 49 min | ||||
| Practice Test 1-Version 3 + answers + Movie |
Test1v3 and answers, and explanatory Movie of Jasperse Going Through it | ||||
| Practice Test 1-Version 4 + answers + Movie |
Test1v4 and answers, and explanatory Movie of Jasperse Going Through it . 33 min | ||||
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| Test 2 Radical Halogenation, Basic Principles of Reactivity, Stereochemistry, SN2/SN1/E2/E1 |
Test 2 Radical Halogenation, Basic Principles of Reactivity, Stereochemistry, and SN2/SN1/E2/E1 reactions of Alkyl Halides |
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| Relevant Test 2notes | Pre-Printable Lecture Notes that Were Used in These Test 2 Lecture Movies | ||||
| 11 | M | 9/23 | OChem-Reactions Lecture 1 | 4:1-5 | p1-7 Radical Halogenation Mech; Bond Strengths; Radical Stabilities; |
| 12 | W | 9/25 | OChem -Reactions Lecture 2 | 4:6 | p7-11 Rate Laws, Transition States, Stability-Reactivity Principles. Radical Brominations. Major product, mechanism, structural isomers. |
| 13 | F | 9/27 | OChem -Reactions Lecture 3 |
4:7-14 | p11-18 Radical Brominations. Product, mechanism. Stability patterns for radicals/cations/anions. Stability-reactivity principles. |
| PS1: Radical Practice Set Problems Radical Practice Video |
Br2/hv Products/Mechanisms Practice and Answers and Video | ||||
| Quiz ch 4-Radical (Required) | Quiz ch 4-Radical (Required, take picture of page with answers and email) | ||||
| Finish Sapling Chapter (required) | |||||
| 14 |
M | 9/30 | 5:1-5 | p1-3 , Chiral Carbons; Chiral vs achiral; Same vs Enantiomers; Attachment Priorities; R/S Designation | |
| PS2: Stereochem Practice Problems Stereochem Practice Video |
Stereochem Practice and Answers and Video R/S; Chiral vs Achiral; and Same/Enantiomer/Diastereomer Practice Problems | ||||
| 15 | W | 10/2 | OChem - Stereo Lecture 2 | 6-16 | p3-5 Chiral Carbons; Attachment Priorities; R/S Designation; Drawing Chiral Molecules. |
| Stereochem Practice Video | Stereochem Practice and Answers and Video | ||||
| 16 | F | 10/4 | OChem - Stereo Lecture 3 | 17-28 | p4-10 Racemic mixtures and Optical Activity. Conformations + Chirality; Planes of Symmetry; Meso; Cis/Trans Diastereomers vs Enantiomers; Recognizing Chiral vs Meso |
| Stereochem Practice Video | Stereochem Practice and Answers and Video | ||||
| Quiz ch 7-Stereo (Required) | Quiz ch 7-Stereo (Required. Print page, answer, take picture, and email to Jasperse) | ||||
| Finish Sapling Chapter (required) | |||||
| 17 | M | 10/7 | Stereo-4 RX-Sn-E Lecture 1 (2018 video: 2019 video failed) |
6:1-5 | p10-11 Stereo (1-19min) p1-6 Alkyl Halides. Reaction preview; Alkyl/Vinyl/Aryl/Allyl Classification; 1º/2º/3º Classification; overview of SN2/SN1/E2/E1 reactions; SN2 reactions and mechanism |
| 18 | W | 10/9 | OChem -Sn-E Lecture 2 | 6:6-17 | p6-10 SN2 Reaction. Product Prediction, Structural Factors. Ranking. Inversion. Mechanisms. |
| 19 | F | 10/11 | OChem -Sn-E Lecture 3 | 6:18-26 | p11-15 SN1 Reactions. |
| PS3: Mechanism Practice Set Mechanism Practice Video |
Extra Mechanism and Product Prediction Problems and Answers and Video | ||||
| 20 | W | 10/16 | OChem -Sn-E Lecture 4 | 6:27-31 | p16-23. E1, E2 Reactions. Zaytsev's Rule. Using Anion/Neutral and 1º, 2º, 3º to diagnose among SN2/E2/SN1/E1 |
| 21 | F | 10/18 | Practice Problems NOT completed in class, 2019 OChem -Sn-E Lecture 5 (71 min. Main lecture; this is 2018 version, my 2019 lecture recording failed, but this covers pretty much the same content) |
6:32-41 | 71 minutes. p20-29. E2 Stereochemistry; Diagnosing Reaction Types; Two-Step Synthesis Design; E1 + E2 Mechanisms; Ranking Problems |
| Finish Sapling Chapter (required) | |||||
| PS3: Mechanism Practice Video | PS3: Extra Mechanism and Product Prediction Problems and Answers and Video | ||||
| PS2: Stereochem Practice Video | PS2: Stereochem Practice and Answers and Video R/S; Chiral vs Achiral; and Same/Enantiomer/Diastereomer Practice Problems | ||||
| PS1: Radical Bromination Practice Video | PS1: Br2/hv Products/Mechanisms Practice and Answers and Video | ||||
| Test 2 Checklist PDF | Print This Checklist. Am I missing anything? | ||||
| Test 2 Skills/Competencies | Can I do all of this? | ||||
| Test 2 Preview | Test 2 Preview - 6 minutes | ||||
| Practice Test 2-Version 1 + answers + Movie |
Test2v1 and answers, Practice Test 2-Version 1-Movie of Jasperse Going Through it | ||||
| Practice Test 2-Version 2 + answers + Movie |
Test2v2 and answers, Practice Test 2-Version 2-Movie of Jasperse Going Through it | ||||
| Practice Test 2-Version 3 + answers + Movie |
Test2v3 and answers, Regular Panopto Movie of Jasperse Going Through it. 34 min | ||||
| Practice Test 2-Version 4 + answers + Movie |
Test2v4 and answers, Regular Panopto Movie of Jasperse Going Through it. 28 min | ||||
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| Test 3: ALKENES | Test 3: Alkenes. Properties, Synthesis, Reactions | ||||
| Relevant Test 3 notes | Pre-Printable Lecture Notes that Were Used in These Test 3 Lecture Movies | ||||
| 22 | W | 10/23 | OChem Alkenes Lecture 1 |
7:1-11 | Nonreactive "Strong acid" anions. p1-5. Intro to alkenes, (EU), Hydrogenation; Alkene Nomenclature; E/Z stereochem |
| 23 | F | 10/25 | OChem Alkenes Lecture 2 |
7:12-23 | p5-11 Alkene Stabilities; Heats of Hydrogenation/Combustion; Bulky Bases/Normal Bases for Hofmann/Zaytsev Elimination |
| 24 | M | 10/28 | OChem Alkenes Lecture 3 | 7:18-25 | p12-16 Alkene Formation. From Alcohols via Acid-Catalyzed E1. Mechanism Recognition. |
| Practice Set 1 Problems Practice Set Movie |
Extra Practice 1 and Answers and Movie | ||||
| Finish Sapling Chapter (required) | |||||
| 25 | W | 11/30 | OChem Alkenes Reactions 1 |
8:1-9 | p1-13; Overview, Intro, Addition reactions to Alkenes. Addition of (Markovnickov and Anti-Markovnikov); Acid-Catalyzed HOH Addn; |
| Practice Set 2 Problems Practice set Movie |
Extra Mechanisms Practice and Answers and Movie | ||||
| 26 | F | 11/1 | OChem Alkenes Reactions 2 | 8:10-18 | p13-18 Acid-Catalyzed HOH Addn; Oxymercuration/Demercuration; Anti-Markovnikov Hydroboration-Oxidation |
| 27 | M | 11/4 | OChem Alkenes Reactions 3 | 8:19-21 | 19-23 Synthesis Design, H2 addn; Br2 addn |
| Practice Set 3 Problems Practice Set 3 Movie |
Alkene Reactions Practice and Answers and Movie | ||||
| 28 | W | 11/6 | OChem Alkenes Reactions 4 |
8:22-36 | 23-28 Br2 and Br2/H2O additions and mechanisms; epoxidation; Cis and Trans Dihydroxylation; Stereospecific Rxns |
| 29 | F | 11/8 | 2018 5a: pick up from here at ~24 minutes: OChem Alkenes Reactions 5 (this is 2018 version. 2019 recording failed) Practice Problems NOT completed in class, 2019 |
8:35-41 | p28-33. Dihydroxylation, Ozonolysis. Stereospecific Alkene Reactions. Synthetic Design. |
| Practice Set 4 Problems Practice Set 4 Movie |
Synthesis Design, Product Prediction, Stereochemistry, and other T3 Practice Problems and Answers and Movie | ||||
| Finish Sapling Chapter (required) | |||||
| 1. Test 3 Extra Practice 1 and Answers and Movie 2. Test 3 Extra Mechanisms Practice and Answers and Movie 3. Test 3 Alkene Reactions Practice and Answers and Movie 4. Test 3 Extra Synthesis Practice (6 pages) and Answers and Movie |
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| Test 3 Checklist PDF | Print This Checklist. Am I missing anything? | ||||
| Test 3 Skills/Competencies | Can I do all of this? | ||||
| Test 3 Preview | Test preview | ||||
| Practice Test 3 V1 + answers + Movie |
Test and answers, Practice Test 3-Version 1-Movie of Jasperse Going Through it | ||||
| Practice Test 3 V2 + answers + Movie |
Test and answers, Practice Test 3-Version 2-Movie of Jasperse Going Through it | ||||
| Practice Test 3 V3 + answers + Movie |
Test and answers, Practice Test 3-Version 3-Movie of Jasperse Going Through it. 36 min | ||||
| Practice Test 3 V4 + answers + Movie |
Test and answers, Practice Test 3-Version 4-Movie of Jasperse Going Through it. 33 min | ||||
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| Test 4: Conjugation and Aromatics | Conjugation, Aromatics, and Reactions of Aromatics | ||||
| Relevant Test 4 Notes | Pre-Printable Lecture Notes that Were Used in These Test 4 Lecture Movies | ||||
| 30 | F | 11/15 | OChem Conjugation Lecture 1 |
p1-6 Conjugation: Introduction, impact on stability, reactivity, hybridization, lone-pairs. Conjugated Dienes, allylic cations. 37 min. |
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| 31 | M | 11/18 | OChem Conjugation Lecture 2 (This is 2018 version, covers exact same pages. 2019 audio failed) |
15:1-9 | p7-10 Asymmetric allylic cations can give Two Products. 1,2/1,4-Addn to Dienes. |
| 32 | W | 11/20 | OChem Conjugation Lecture 3 | 15:10-13 | p11-17. Allylic Cations. Allylic Radicals (NBS bromination). Allylic anions. Allylic SN2. Diels-Alder Intro. (p15,16 skip) |
| PS1 Problems and Movie | HBr Addition to Dienes and NBS Allylic Bromination Practice and Answers and Movie | ||||
| 33 | F | 11/22 | Diels Alder; Aromatics 1 | 15:14-20 16:1-12 |
p17-19. Diels-Alder Reactions of Conjugated Dienes. p1-6 Aromaticity,Huckel's Rule,Ions,Heterocycles |
| PS2 Problems and Movie | Conjugation-Allylic-DielsAlder Chapter Practice and Answers and Movie | ||||
| 34 | M | 11/25 | Aromatics 2 | 16:13-19 | p6-9 Nomenclature, N-Basicity p1-7 Intro to Aromatic Reactions 65 minutes |
| 35 | M | 12/2 | Aromatics Reactions 1 70 minutes |
p7-13 | |
| 36 | W | 12/4 | Aromatics Reactions 2 | p13-17 | |
| PS3 Problems and Movie | Aromatic Substitution Mechanisms (Products Provided) Practice and Answers and Movie | ||||
| 37 | F | 12/6 | Aromatics Reactions 3 | p18-21 | |
| PS4 Problems and Movie | Aromatic Substitution Product Prediction/Mechanisms/Synthesis Design Practice and Answers and Movie | ||||
| 1. PS#1: HBr Addition to Dienes and NBS Allylic Bromination Practice and Answers and Movie 2. PS#2: Conjugation-Allylic-DielsAlder Chapter Practice and Answers and Movie 3. PS#3: Aromatic Substitution Mechanisms (Products Provided) Practice and Answers and Movie 4. PS#4:Aromatic Substitution Product Prediction/Mechanisms/Synthesis Design Practice and Answers and Movie |
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| Test 4 Checklist PDF | Print This Checklist. Am I missing anything? | ||||
| Test 4 Skills/Competencies | Can I do all of this? | ||||
| Test4Preview | |||||
| Practice Test 4-Version 1 + answers + Movie |
Test and answers, Movie of Jasperse Going Through it. 50 min | ||||
| Practice Test 4-Version 2 + answers + Movie |
Test and answers, Movie of Jasperse Going Through it. 42 min | ||||
| Practice Test 4-Version 3 + answers + Movie |
Test and answers, Movie of Jasperse Going Through it. 50 min | ||||
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| Final Exam Practice Tests | |||||
| Final Exam Preview | |||||
| Organic I Review | |||||
| Final Exam Practice Version 1 + answers + Movie |
Test and answers, Movie of Jasperse Going Through it. 50 min | ||||
| Final Exam Practice Version 2 + answers + Movie |
Test and answers, Movie of Jasperse Going Through it. 50 min | ||||